polypropylene production
The certain CO., Ltd. (hereinafter referred to as party A) signed the following contract with Shandong Xunda chemical group CO., Ltd. (hereinafter referred to as party B) according to refining catalyst for propylene that 100 thousand t/year propylene project equipment required.

Z919
Ambient Temperature Zinc Oxide Sulfur Remover
|
Quality standards |
|
|
Appearance |
Gray strip |
|
Specification, mm |
Φ (3~5) × (5~25) |
|
Bulk density, Kg/L |
0.8~1.1 |
|
Compressive strength, N/cm |
≥70 |
|
Sulfur capacity, %(m/m) |
≥10.0 |

RAs988
Strip Shaped Arsenic Remover
|
Appearance |
Black strip |
|
Specification, mm |
Φ (3~5) × (5~10) |
|
Bulk density, kg/L |
0.9~1.2 |
|
Compressive strength, N/cm |
≥90 |
|
Arsenic removal capacity, %(m/m) |
≥9 |
|
P removal capacity%(m/m) |
≥1 |

loading scheme
1. Inlet propylene quantity: 12.5t/h, about 28m3/h
2. Pipeline size of inlet and outlet: DN100
3. Composition order and operating situation of refining system:
Caustic soda tower (2, connection)-hydrolysis and desulfurization tower (1, hydrolysis at lower, desulfurization at upper)-3A molecular sieve tower (2, one start and one preparation)-arsenic removal tower (1)-3A molecular sieve tower (2, one start and one preparation), total 8 units, actual operation is 6
4. Material indexes of propylene:
H2O (<50ppm), S (<5ppm), O2 (<10ppm), CO2 (<10ppm), CO (<5ppm), As (<1ppm), propyne (<5ppm), diene (<20ppm), C4 composition (no)
5. Propylene indexes after refining
H2O (<10ppm), S (<1ppm), O2 (<5ppm), CO2 (<5ppm), CO (<2ppm), As (<0.03ppm), propyne (<2ppm), diene (<5ppm), C4 composition (no)

performance and effect
Various requirements of operating situation and operating elasticity that based on the requirements of design base, the guaranteed values of each refining agent performance are as follows:
Lifetime: at the beginning of the introduction, the lifetime of A911 COS hydrolysis agent and Z919 refining desulfurizer is 3 years, the lifetime of 3A molecular sieve is more than 4 years, the lifetime of Ras988 arsenic remover is more than 5 years
Impurities removal performance: at the condition of processing design, the impurities removal accuracy of propylene inlet and outlet see in table 2
Table pre-removal accuracy of impurities in propylene refining unit
|
Composition |
Inlet content |
Outlet content |
|
Total sulfur |
<5ppm |
<1ppm |
|
As |
<1ppm |
<0.03ppm |
|
H2O |
<50ppm |
<10ppm |

