Your Professional Hydrodesulfurization Catalyst Supplier

 

Shandong Xunda manufactures hydrodesulfurization and hydrorefining catalysts for petroleum refining, petrochemical processing, fuel upgrading, and related hydrogenation applications.

 

Our catalyst portfolio covers Co-Mo, W-Ni, Mo-W-Ni, Mo-Ni, Ni, and precious-metal active systems, combined with alumina, silica-alumina, and modified support structures tailored to distinct feedstocks and process requirements. Material selection matches feed composition, sulfur level, reactor operating windows, and target product specifications.

 

 
  • Kerosene Hydrodesulfurization Catalyst
    Kerosene hydrodesulfurization (HDS) catalysts are specialized refining catalysts utilized in fixed-bed catalytic reactors to remove sulfur, nitrogen, and other heteroatom impurities from kerosene and
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  • Ultra Deep HDS Catalyst
    Ultra Deep HDS Catalyst is a supported hydrotreating catalyst engineered for the deep removal of sulfur compounds from petroleum and refinery feedstocks under hydrogen-rich conditions.
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  • Deep Hydrodesulfurization Catalyst
    This multi-metallic hydrotreating catalyst is engineered with a molybdenum-tungsten-nickel active phase supported on modified alumina. It is specifically designed for refinery units performing diesel
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Standard Physical and Chemical Property Benchmarks

Parameter

Technical Consideration and Typical Ranges

Active Metals

Co-Mo, Ni-Mo, W-Ni, Mo-W-Ni, and precious metal systems

Support Material

Alumina, silica-alumina, or modified composite carriers

Metal Loading

Governs active-site density and catalytic activity

Surface Area

Correlates with active-component dispersion (150 to 250 m2/g typical range)

Pore Volume

Affects reactant diffusion and larger molecule accessibility (0.45 to 0.60 cm3/g typical range)

Bulk Density

Essential for calculating reactor loading weight and volume

Crushing Strength

Determines catalyst bed integrity and resistance to crushing (>90 to 100 N for standard alumina extrudates)

Catalyst Shape

Influences pressure drop, void fraction, and mass transfer (Cylinders, Trilobes/Clover, Spheres)

 

Primary Industrial Applications
 

Diesel Hydrotreating

Reduces sulfur and aromatics in middle distillates to meet stringent environmental fuel standards using systems such as XDH-3.

Gasoline Hydrorefining

Balances sulfur removal with olefin retention and octane preservation using formulations such as SH-1.

Wax Hydrofining

Purifies paraffin wax by removing trace impurities and color bodies via specialized carriers like XDH-1 and XDH-4.

Distillate Hydroprocessing

Pre-treats catalytic cracking feedstocks and refinery intermediates across various petroleum fractions.

 

Co-Mo Hydrogenation Catalyst

 

Support Morphology, Pore Dynamics and Mechanical Integrity

The support functions as an active structural component rather than an inert carrier.

 

Pore Structure and Diffusion: Different support systems (activated alumina, modified alumina, silica-alumina) control pore-diameter distribution and active-metal dispersion, ensuring accessibility for large molecular structures in heavy fractions.

 

Mechanical Stability: Catalyst geometry and mechanical strength are engineered to withstand reactor loading impact, long-term bed weight, thermal cycling, and fluid-induced shear stress. High mechanical integrity minimizes catalyst breakage, preventing fine generation and subsequent pressure drop buildup across the reactor bed.

 

How to Select a Hydrodesulfurization Catalyst

Selecting an industrial hydrotreating catalyst requires evaluating the process environment from the feedstock inward, rather than relying on generalized product categories.

 

Feedstock Identification

 

Identify the hydrocarbon stream entering the hydroprocessing unit. Typical feedstocks include:

  • Gasoline and naphtha
  • Diesel and gas oil
  • Kerosene and jet fuel fractions
  • Paraffin wax
  • Petroleum distillates

Sulfur Content and Sulfur Species

 

While total sulfur concentration is a primary baseline, the specific organosulfur compounds present dictate the required catalytic activity. Feedstocks may contain:

  • Mercaptans and simple sulfides
  • Disulfides
  • Thiophenic compounds
  • Benzothiophenes and dibenzothiophenes
  • Refractory polyaromatic sulfur species

Operating Conditions

 

The operating window governs catalyst activity, reaction kinetics, and run length. Key parameters include:

  • Reactor temperature profile
  • Hydrogen partial pressure and total pressure
  • Liquid hourly space velocity (LHSV)
  • Hydrogen-to-oil ratio
  • Catalyst bed volume and reactor configuration

Product Sulfur Specifications

 

The target residual sulfur level in the treated product determines the required reactor severity and catalyst volume. Specifying the target ppm or weight percentage ensures proper formulation matching.

 

Customization and Technical Support

Every refinery unit operates under unique constraints regarding feedstock composition, spatial velocity, and hydrogen availability. We support engineering evaluations by tailoring catalyst parameters:

 
 

Formulation Customization

Adjusting active metal ratios or support acidity to address specific poisoning agents or activity targets.

 
 
 

Particle Geometry Optimization

Supplying specific extrudate diameters or multilobe shapes to optimize reactor pressure drop and void fraction.

 
 
 

Technical Collaboration

Reviewing operational data to ensure smooth catalyst loading, activation, and performance alignment.

 

 

Manufacturing and Quality Control

 

Consistent industrial performance requires rigorous manufacturing controls and analytical testing.

Production Infrastructure

Three dedicated catalyst production lines with a combined annual capacity of approximately 9,500 tons.

Quality Verification

Analytical testing evaluates chemical composition, metal loading, surface area, pore volume, bulk density, particle size distribution, moisture characteristics, and mechanical crushing strength.

Batch Traceability

Every production lot is verified against technical specifications before dispatch with accompanying quality documentation.

 

Frequently Asked Questions

 

Q: How should spent HDS catalysts be handled, or do you provide regeneration and recycling guidance?

A: While our primary supply scope is fresh, high-activity commercial catalysts, our technical team provides handling guidelines for spent catalyst discharge during unit turnarounds. We assist refinery clients in understanding metal recovery pathways (such as recovering molybdenum, nickel, cobalt, and tungsten values) and provide safety recommendations for spent bed unloading and safe disposal in compliance with environmental regulations.

Q: What is the standard shelf life and storage requirement for fresh alumina and silica-alumina supported catalysts?

A: Unopened catalysts stored in standard sealed steel drums or jumbo bags under dry, weather-protected warehouse conditions maintain their chemical stability and mechanical integrity for a minimum of 24 to 36 months. We recommend keeping packaging tightly sealed prior to reactor loading to prevent moisture adsorption, which can affect initial catalyst activation and reactor heat-up procedures.

Q: What is the typical activation and sulfiding procedure required before putting fresh HDS catalysts into service?

A: Most industrial hydrodesulfurization catalysts are supplied in their oxide form and require in-situ or ex-situ sulfiding (typically using dimethyl disulfide or sulfur-spiked feedstocks) to convert active metal oxides into active metal sulfides. We supply detailed startup, drying, reduction, and sulfiding technical guidelines tailored to each specific catalyst family (such as Co-Mo versus W-Ni systems) to ensure optimal initial activity and prevent premature deactivation.

Q: How do changes in feedstock heavy metal contaminants (like nickel, vanadium, and arsenic) affect HDS catalyst cycle length?

A: Heavy metals present in heavy gas oils or cracked residues can deposit on the external surface and pore mouths of hydrotreating catalysts, causing pore blockage and gradual active-site poisoning. If your feedstock contains high levels of metallic contaminants, sharing this data allows our engineering team to recommend a tailored guard-bed configuration or a catalyst system with optimized macroporosity to maintain cycle length.

As one of the most professional hydrodesulfurization catalyst manufacturers and suppliers in China, we're featured by quality products and good price. Please rest assured to buy high-grade hydrodesulfurization catalyst from our factory.

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